Concrete retarders, also known as retarding admixtures, play a crucial role in construction by slowing down the setting process of cement-based mixtures. Let’s delve into the mechanisms, types, and effects of these additives.
Concrete retarders function by temporarily pausing the hydration reactions in cement paste. Four mechanisms contribute to this process:
i) Adsorption
ii) Nucleation
iii) Complexation
iv) Precipitation
Concrete retarders come in two main types:
1. Organic Retarder
Phosphonates, lignosulphonates, sugars, hydroxycarboxylic acids.
2. Inorganic Retarder
Salts of Pb, Zn, Cu, As, Sb; borates; phosphonates.
Retarding admixtures impact various properties of concrete:
Strength : Reduces initial compressive strength.
Slump Loss : Improves initial workability by decreasing slump loss.
Durability : Comparable durability to untreated concrete when properly cured.
Workability and Rheological Values : Marginally affects workability, leading to a higher initial slump.
Volume Deformation : Does not significantly alter creep or drying shrinkage.
Air Entrainment : Some retarding admixtures may reduce air content.
Bleeding : Increases the risk of bleeding in concretes.
Freeze-Thaw Cycles : Air-entraining admixtures enhance resistance to freezing and thawing.
Heat of Hydration : Delays the peak temperature rise in concrete.
Concrete retarders find applications in various scenarios:
Concrete retarders offer a valuable solution to manage the setting time of concrete in challenging conditions. While they bring several advantages, careful evaluation and dosage consideration are essential to avoid construction setbacks. Trial mixes with the specific cement used are recommended for optimal results.